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mmazloff |
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C $Header: $ |
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C $Name: $ |
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#include "BLING_OPTIONS.h" |
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C-- File bling_carbon_chem.F: |
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C-- Contents |
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C-- o CALC_PCO2 |
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C-- o CALC_PCO2_APPROX |
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C-- o CARBON_COEFFS |
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C-- o CARBON_COEFFS_PRESSURE_DEP |
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CBOP |
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subroutine CALC_PCO2( |
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I donewt,inewtonmax,ibrackmax, |
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I t,s,diclocal,pt,sit,ta, |
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I k1local,k2local, |
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I k1plocal,k2plocal,k3plocal, |
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I kslocal,kblocal,kwlocal, |
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I ksilocal,kflocal, |
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I k0local, fugflocal, |
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I fflocal,btlocal,stlocal,ftlocal, |
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U pHlocal,pCO2surfloc, |
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I i,j,k,bi,bj,myIter,myThid ) |
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C !DESCRIPTION: |
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C surface ocean inorganic carbon chemistry to OCMIP2 |
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C regulations modified from OCMIP2 code; |
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C Mick Follows, MIT, Oct 1999. |
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C Apr 2011: fix vapour bug (following Bennington) |
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implicit none |
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C === Global variables === |
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#include "SIZE.h" |
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#include "DYNVARS.h" |
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#include "EEPARAMS.h" |
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#include "PARAMS.h" |
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#include "GRID.h" |
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#include "FFIELDS.h" |
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#include "BLING_VARS.h" |
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C == Routine arguments == |
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C diclocal = total inorganic carbon (mol/m^3) |
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C where 1 T = 1 metric ton = 1000 kg |
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C ta = total alkalinity (eq/m^3) |
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C pt = inorganic phosphate (mol/^3) |
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C sit = inorganic silicate (mol/^3) |
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C t = temperature (degrees C) |
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C s = salinity (PSU) |
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INTEGER donewt |
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INTEGER inewtonmax |
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INTEGER ibrackmax |
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_RL t, s, pt, sit, ta |
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_RL pCO2surfloc, diclocal, pHlocal |
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_RL fflocal, btlocal, stlocal, ftlocal |
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_RL k1local, k2local |
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_RL k1plocal, k2plocal, k3plocal |
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_RL kslocal, kblocal, kwlocal, ksilocal, kflocal |
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_RL k0local, fugflocal |
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INTEGER i,j,k,bi,bj,myIter |
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INTEGER myThid |
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CEOP |
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C == Local variables == |
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C INPUT |
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C phlo= lower limit of pH range |
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C phhi= upper limit of pH range |
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C atmpres = atmospheric pressure in atmospheres (1 atm==1013.25mbar) |
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C OUTPUT |
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C co2star = CO2*water (mol/m^3) |
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C pco2surf = oceanic pCO2 (ppmv) |
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C --------------------------------------------------------------------- |
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C OCMIP NOTE: Some words about units - (JCO, 4/4/1999) |
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C - Models carry tracers in mol/m^3 (on a per volume basis) |
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C - Conversely, this routine, which was written by |
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C observationalists (C. Sabine and R. Key), passes input |
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C arguments in umol/kg (i.e., on a per mass basis) |
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C - I have changed things slightly so that input arguments are in |
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C mol/m^3, |
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C - Thus, all input concentrations (diclocal, ta, pt, and st) should be |
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C given in mol/m^3; output arguments "co2star" and "dco2star" |
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C are likewise be in mol/m^3. |
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C --------------------------------------------------------------------- |
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_RL phhi |
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_RL phlo |
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_RL c |
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_RL a |
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_RL a2 |
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_RL da |
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_RL b |
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_RL b2 |
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_RL db |
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_RL fn |
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_RL df |
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_RL deltax |
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_RL x |
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_RL x2 |
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_RL x3 |
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_RL xmid |
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_RL ftest |
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_RL htotal |
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_RL htotal2 |
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_RL co2star |
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_RL phguess |
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_RL fco2 |
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INTEGER inewton |
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INTEGER ibrack |
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INTEGER hstep |
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_RL fni(3) |
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_RL xlo |
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_RL xhi |
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_RL xguess |
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_RL k123p |
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_RL k12p |
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_RL k12 |
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c --------------------------------------------------------------------- |
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c import donewt flag |
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c set donewt = 1 for newton-raphson iteration |
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c set donewt = 0 for bracket and bisection |
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c --------------------------------------------------------------------- |
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C Change units from the input of mol/m^3 -> mol/kg: |
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c (1 mol/m^3) x (1 m^3/1024.5 kg) |
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c where the ocean mean surface density is 1024.5 kg/m^3 |
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c Note: mol/kg are actually what the body of this routine uses |
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c for calculations. Units are reconverted back to mol/m^3 at the |
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c end of this routine. |
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c --------------------------------------------------------------------- |
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c To convert input in mol/m^3 -> mol/kg |
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pt=pt*permil |
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sit=sit*permil |
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ta=ta*permil |
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diclocal=diclocal*permil |
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c --------------------------------------------------------------------- |
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c set first guess and brackets for [H+] solvers |
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c first guess (for newton-raphson) |
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phguess = phlocal |
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c bracketing values (for bracket/bisection) |
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phhi = 10.0 |
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phlo = 5.0 |
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c convert to [H+]... |
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xguess = 10.0**(-phguess) |
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xlo = 10.0**(-phhi) |
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xhi = 10.0**(-phlo) |
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xmid = (xlo + xhi)*0.5 |
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c---------------------------------------------------------------- |
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c iteratively solve for [H+] |
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c (i) Newton-Raphson method with fixed number of iterations, |
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c use previous [H+] as first guess |
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c select newton-raphson, inewt=1 |
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c else select bracket and bisection |
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cQQQQQ |
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if( donewt .eq. 1)then |
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c......................................................... |
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c NEWTON-RAPHSON METHOD |
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c......................................................... |
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x = xguess |
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cdiags |
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c WRITE(0,*)'xguess ',xguess |
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cdiags |
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do inewton = 1, inewtonmax |
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c set some common combinations of parameters used in |
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c the iterative [H+] solvers |
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x2=x*x |
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x3=x2*x |
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k12 = k1local*k2local |
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k12p = k1plocal*k2plocal |
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k123p = k12p*k3plocal |
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c = 1.0 + stlocal/kslocal |
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a = x3 + k1plocal*x2 + k12p*x + k123p |
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a2=a*a |
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da = 3.0*x2 + 2.0*k1plocal*x + k12p |
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b = x2 + k1local*x + k12 |
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b2=b*b |
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db = 2.0*x + k1local |
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c Evaluate f([H+]) and f_prime([H+]) |
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c fn = hco3+co3+borate+oh+hpo4+2*po4+silicate+hfree |
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c +hso4+hf+h3po4-ta |
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fn = k1local*x*diclocal/b + |
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& 2.0*diclocal*k12/b + |
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& btlocal/(1.0 + x/kblocal) + |
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& kwlocal/x + |
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& pt*k12p*x/a + |
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& 2.0*pt*k123p/a + |
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& sit/(1.0 + x/ksilocal) - |
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& x/c - |
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& stlocal/(1.0 + kslocal/x/c) - |
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& ftlocal/(1.0 + kflocal/x) - |
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& pt*x3/a - |
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& ta |
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c df = dfn/dx |
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cdiags |
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c WRITE(0,*)'values',b2,kblocal,x2,a2,c,x |
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cdiags |
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df = ((k1local*diclocal*b) - k1local*x*diclocal*db)/b2 - |
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& 2.0*diclocal*k12*db/b2 - |
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& btlocal/kblocal/(1.0+x/kblocal)**2. - |
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& kwlocal/x2 + |
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& (pt*k12p*(a - x*da))/a2 - |
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& 2.0*pt*k123p*da/a2 - |
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& sit/ksilocal/(1.0+x/ksilocal)**2. + |
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& 1.0/c + |
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& stlocal*(1.0 + kslocal/x/c)**(-2.0)*(kslocal/c/x2) + |
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& ftlocal*(1.0 + kflocal/x)**(-2.)*kflocal/x2 - |
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& pt*x2*(3.0*a-x*da)/a2 |
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c evaluate increment in [H+] |
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deltax = - fn/df |
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c update estimate of [H+] |
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x = x + deltax |
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cdiags |
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c write value of x to check convergence.... |
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c write(0,*)'inewton, x, deltax ',inewton, x, deltax |
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c write(6,*) |
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cdiags |
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end do |
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c end of newton-raphson method |
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c.................................................... |
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else |
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c.................................................... |
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C BRACKET AND BISECTION METHOD |
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c.................................................... |
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c (ii) If first step use Bracket and Bisection method |
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c with fixed, large number of iterations |
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do ibrack = 1, ibrackmax |
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do hstep = 1,3 |
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if(hstep .eq. 1)x = xhi |
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if(hstep .eq. 2)x = xlo |
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if(hstep .eq. 3)x = xmid |
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c set some common combinations of parameters used in |
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c the iterative [H+] solvers |
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x2=x*x |
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x3=x2*x |
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k12 = k1local*k2local |
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k12p = k1plocal*k2plocal |
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k123p = k12p*k3plocal |
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c = 1.0 + stlocal/kslocal |
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a = x3 + k1plocal*x2 + k12p*x + k123p |
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a2=a*a |
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da = 3.0*x2 + 2.0*k1plocal*x + k12p |
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b = x2 + k1local*x + k12 |
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b2=b*b |
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db = 2.0*x + k1local |
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c evaluate f([H+]) for bracketing and mid-value cases |
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fn = k1local*x*diclocal/b + |
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& 2.0*diclocal*k12/b + |
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& btlocal/(1.0 + x/kblocal) + |
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& kwlocal/x + |
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& pt*k12p*x/a + |
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& 2.0*pt*k123p/a + |
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& sit/(1.0 + x/ksilocal) - |
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& x/c - |
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& stlocal/(1.0 + kslocal/x/c) - |
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& ftlocal/(1.0 + kflocal/x) - |
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& pt*x3/a - |
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& ta |
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fni(hstep) = fn |
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end do |
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c now bracket solution within two of three |
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ftest = fni(1)/fni(3) |
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if(ftest .gt. 0.0)then |
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xhi = xmid |
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else |
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xlo = xmid |
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end if |
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xmid = (xlo + xhi)*0.5 |
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cdiags |
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c write value of x to check convergence.... |
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c WRITE(0,*)'bracket-bisection iteration ',ibrack, xmid |
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cdiags |
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end do |
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c last iteration gives value |
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x = xmid |
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c end of bracket and bisection method |
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c.................................... |
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end if |
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c iterative [H+] solver finished |
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c---------------------------------------------------------------- |
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c now determine pCO2 etc... |
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c htotal = [H+], hydrogen ion conc |
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htotal = x |
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C Calculate [CO2*] as defined in DOE Methods Handbook 1994 Ver.2, |
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C ORNL/CDIAC-74, dickson and Goyet, eds. (Ch 2 p 10, Eq A.49) |
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htotal2=htotal*htotal |
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co2star=diclocal*htotal2/(htotal2 + k1local*htotal |
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& + k1local*k2local) |
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phlocal=-log10(htotal) |
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c --------------------------------------------------------------- |
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c Add two output arguments for storing pCO2surf |
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c Should we be using K0 or ff for the solubility here? |
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c --------------------------------------------------------------- |
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fco2 = co2star / k0local |
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pCO2surfloc = fco2/fugflocal |
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C ---------------------------------------------------------------- |
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C Reconvert units back to original values for input arguments |
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C no longer necessary???? |
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C ---------------------------------------------------------------- |
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c Reconvert from mol/kg -> mol/m^3 |
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pt=pt/permil |
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sit=sit/permil |
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ta=ta/permil |
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diclocal=diclocal/permil |
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RETURN |
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END |
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C---+----1----+----2----+----3----+----4----+----5----+----6----+----7-|--+----| |
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CBOP |
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subroutine CALC_PCO2_APPROX( |
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I t,s,diclocal,pt,sit,ta, |
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I k1local,k2local, |
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I k1plocal,k2plocal,k3plocal, |
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I kslocal,kblocal,kwlocal, |
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I ksilocal,kflocal, |
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I k0local, fugflocal, |
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I fflocal,btlocal,stlocal,ftlocal, |
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U pHlocal,pCO2surfloc,co3local, |
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I i,j,k,bi,bj,myIter,myThid ) |
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C !DESCRIPTION: |
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C *==========================================================* |
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C | SUBROUTINE CALC_PCO2_APPROX | |
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C *==========================================================* |
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C CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC |
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C C New efficient pCO2 solver, Mick Follows CC |
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C C Taka Ito CC |
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C C Stephanie Dutkiewicz CC |
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C C 20 April 2003 CC |
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C CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC |
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C Apr 2011: fix vapour bug (following Bennington) |
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C Oct 2011: add CO3 extimation and pass out |
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implicit none |
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C === Global variables === |
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#include "SIZE.h" |
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#include "DYNVARS.h" |
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#include "EEPARAMS.h" |
| 355 |
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#include "PARAMS.h" |
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#include "GRID.h" |
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#include "FFIELDS.h" |
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#include "BLING_VARS.h" |
| 359 |
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|
| 360 |
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C == Routine arguments == |
| 361 |
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C diclocal = total inorganic carbon (mol/m^3) |
| 362 |
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C where 1 T = 1 metric ton = 1000 kg |
| 363 |
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C ta = total alkalinity (eq/m^3) |
| 364 |
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C pt = inorganic phosphate (mol/^3) |
| 365 |
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C sit = inorganic silicate (mol/^3) |
| 366 |
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C t = temperature (degrees C) |
| 367 |
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C s = salinity (PSU) |
| 368 |
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_RL t, s, pt, sit, ta |
| 369 |
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_RL pCO2surfloc, diclocal, pHlocal |
| 370 |
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_RL fflocal, btlocal, stlocal, ftlocal |
| 371 |
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_RL k1local, k2local |
| 372 |
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_RL k1plocal, k2plocal, k3plocal |
| 373 |
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_RL kslocal, kblocal, kwlocal, ksilocal, kflocal |
| 374 |
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_RL k0local, fugflocal |
| 375 |
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_RL co3local |
| 376 |
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INTEGER i,j,k,bi,bj,myIter |
| 377 |
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INTEGER myThid |
| 378 |
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CEOP |
| 379 |
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| 380 |
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C == Local variables == |
| 381 |
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_RL phguess |
| 382 |
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_RL cag |
| 383 |
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_RL bohg |
| 384 |
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_RL hguess |
| 385 |
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_RL stuff |
| 386 |
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_RL gamm |
| 387 |
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_RL hnew |
| 388 |
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_RL co2s |
| 389 |
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_RL h3po4g, h2po4g, hpo4g, po4g |
| 390 |
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_RL siooh3g |
| 391 |
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_RL fco2 |
| 392 |
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| 393 |
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| 394 |
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c --------------------------------------------------------------------- |
| 395 |
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C Change units from the input of mol/m^3 -> mol/kg: |
| 396 |
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c (1 mol/m^3) x (1 m^3/1024.5 kg) |
| 397 |
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c where the ocean mean surface density is 1024.5 kg/m^3 |
| 398 |
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c Note: mol/kg are actually what the body of this routine uses |
| 399 |
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c for calculations. Units are reconverted back to mol/m^3 at the |
| 400 |
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c end of this routine. |
| 401 |
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c To convert input in mol/m^3 -> mol/kg |
| 402 |
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pt=pt*permil |
| 403 |
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sit=sit*permil |
| 404 |
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ta=ta*permil |
| 405 |
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diclocal=diclocal*permil |
| 406 |
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c --------------------------------------------------------------------- |
| 407 |
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c set first guess and brackets for [H+] solvers |
| 408 |
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c first guess (for newton-raphson) |
| 409 |
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phguess = phlocal |
| 410 |
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cmick - new approx method |
| 411 |
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cmick - make estimate of htotal (hydrogen ion conc) using |
| 412 |
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cmick appromate estimate of CA, carbonate alkalinity |
| 413 |
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hguess = 10.0**(-phguess) |
| 414 |
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cmick - first estimate borate contribution using guess for [H+] |
| 415 |
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bohg = btlocal*kblocal/(hguess+kblocal) |
| 416 |
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|
| 417 |
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cmick - first estimate of contribution from phosphate |
| 418 |
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cmick based on Dickson and Goyet |
| 419 |
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stuff = hguess*hguess*hguess |
| 420 |
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& + (k1plocal*hguess*hguess) |
| 421 |
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& + (k1plocal*k2plocal*hguess) |
| 422 |
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& + (k1plocal*k2plocal*k3plocal) |
| 423 |
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h3po4g = (pt*hguess*hguess*hguess) / stuff |
| 424 |
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h2po4g = (pt*k1plocal*hguess*hguess) / stuff |
| 425 |
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hpo4g = (pt*k1plocal*k2plocal*hguess) / stuff |
| 426 |
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po4g = (pt*k1plocal*k2plocal*k3plocal) / stuff |
| 427 |
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|
| 428 |
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cmick - estimate contribution from silicate |
| 429 |
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cmick based on Dickson and Goyet |
| 430 |
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siooh3g = sit*ksilocal / (ksilocal + hguess) |
| 431 |
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|
| 432 |
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cmick - now estimate carbonate alkalinity |
| 433 |
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cag = ta - bohg - (kwlocal/hguess) + hguess |
| 434 |
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& - hpo4g - 2.0 _d 0*po4g + h3po4g |
| 435 |
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& - siooh3g |
| 436 |
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| 437 |
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cmick - now evaluate better guess of hydrogen ion conc |
| 438 |
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cmick htotal = [H+], hydrogen ion conc |
| 439 |
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gamm = diclocal/cag |
| 440 |
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stuff = (1.0 _d 0-gamm)*(1.0 _d 0-gamm)*k1local*k1local |
| 441 |
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& - 4.0 _d 0*k1local*k2local*(1.0 _d 0-2.0 _d 0*gamm) |
| 442 |
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hnew = 0.5 _d 0*( (gamm-1.0 _d 0)*k1local + sqrt(stuff) ) |
| 443 |
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cmick - now determine [CO2*] |
| 444 |
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co2s = diclocal/ |
| 445 |
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& (1.0 _d 0 + (k1local/hnew) + (k1local*k2local/(hnew*hnew))) |
| 446 |
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cmick - return update pH to main routine |
| 447 |
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phlocal = -log10(hnew) |
| 448 |
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|
| 449 |
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c NOW EVALUATE CO32-, carbonate ion concentration |
| 450 |
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c used in determination of calcite compensation depth |
| 451 |
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c Karsten Friis & Mick - Sep 2004 |
| 452 |
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co3local = k1local*k2local*diclocal / |
| 453 |
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& (hnew*hnew + k1local*hnew + k1local*k2local) |
| 454 |
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|
| 455 |
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c --------------------------------------------------------------- |
| 456 |
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c surface pCO2 (following Dickson and Goyet, DOE...) |
| 457 |
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fco2 = co2s/k0local |
| 458 |
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pco2surfloc = fco2/fugflocal |
| 459 |
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| 460 |
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C ---------------------------------------------------------------- |
| 461 |
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c Reconvert from mol/kg -> mol/m^3 |
| 462 |
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pt=pt/permil |
| 463 |
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sit=sit/permil |
| 464 |
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ta=ta/permil |
| 465 |
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diclocal=diclocal/permil |
| 466 |
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| 467 |
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RETURN |
| 468 |
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END |
| 469 |
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| 470 |
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C---+----1----+----2----+----3----+----4----+----5----+----6----+----7-|--+----| |
| 471 |
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CBOP |
| 472 |
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subroutine CARBON_COEFFS( |
| 473 |
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I ttemp,stemp, |
| 474 |
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I bi,bj,iMin,iMax,jMin,jMax,myThid) |
| 475 |
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|
| 476 |
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C !DESCRIPTION: |
| 477 |
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C *==========================================================* |
| 478 |
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C | SUBROUTINE CARBON_COEFFS | |
| 479 |
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C | determine coefficients for surface carbon chemistry | |
| 480 |
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C | adapted from OCMIP2: SUBROUTINE CO2CALC | |
| 481 |
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C | mick follows, oct 1999 | |
| 482 |
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C | minor changes to tidy, swd aug 2002 | |
| 483 |
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C *==========================================================* |
| 484 |
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C INPUT |
| 485 |
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C diclocal = total inorganic carbon (mol/m^3) |
| 486 |
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C where 1 T = 1 metric ton = 1000 kg |
| 487 |
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C ta = total alkalinity (eq/m^3) |
| 488 |
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C pt = inorganic phosphate (mol/^3) |
| 489 |
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C sit = inorganic silicate (mol/^3) |
| 490 |
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C t = temperature (degrees C) |
| 491 |
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C s = salinity (PSU) |
| 492 |
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C OUTPUT |
| 493 |
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C IMPORTANT: Some words about units - (JCO, 4/4/1999) |
| 494 |
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C - Models carry tracers in mol/m^3 (on a per volume basis) |
| 495 |
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C - Conversely, this routine, which was written by observationalists |
| 496 |
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C (C. Sabine and R. Key), passes input arguments in umol/kg |
| 497 |
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C (i.e., on a per mass basis) |
| 498 |
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C - I have changed things slightly so that input arguments are in mol/m^3, |
| 499 |
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C - Thus, all input concentrations (diclocal, ta, pt, and st) should be |
| 500 |
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C given in mol/m^3; output arguments "co2star" and "dco2star" |
| 501 |
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C are likewise be in mol/m^3. |
| 502 |
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C |
| 503 |
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C Apr 2011: fix vapour bug (following Bennington) |
| 504 |
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C-------------------------------------------------------------------------- |
| 505 |
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| 506 |
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implicit none |
| 507 |
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|
| 508 |
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C === Global variables === |
| 509 |
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#include "SIZE.h" |
| 510 |
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#include "DYNVARS.h" |
| 511 |
|
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#include "EEPARAMS.h" |
| 512 |
|
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#include "PARAMS.h" |
| 513 |
|
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#include "GRID.h" |
| 514 |
|
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#include "FFIELDS.h" |
| 515 |
|
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#include "BLING_VARS.h" |
| 516 |
|
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C == Routine arguments == |
| 517 |
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C ttemp and stemp are local theta and salt arrays |
| 518 |
|
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C dont really need to pass T and S in, could use theta, salt in |
| 519 |
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C common block in DYNVARS.h, but this way keeps subroutine more |
| 520 |
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C general |
| 521 |
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_RL ttemp(1-OLx:sNx+OLx,1-OLy:sNy+OLy) |
| 522 |
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_RL stemp(1-OLx:sNx+OLx,1-OLy:sNy+OLy) |
| 523 |
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INTEGER bi,bj,iMin,iMax,jMin,jMax |
| 524 |
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INTEGER myThid |
| 525 |
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CEOP |
| 526 |
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|
| 527 |
|
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C LOCAL VARIABLES |
| 528 |
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_RL t |
| 529 |
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_RL s |
| 530 |
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_RL tk |
| 531 |
|
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_RL tk100 |
| 532 |
|
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_RL tk1002 |
| 533 |
|
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_RL dlogtk |
| 534 |
|
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_RL sqrtis |
| 535 |
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_RL sqrts |
| 536 |
|
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_RL s15 |
| 537 |
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_RL scl |
| 538 |
|
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_RL s2 |
| 539 |
|
|
_RL invtk |
| 540 |
|
|
_RL is |
| 541 |
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_RL is2 |
| 542 |
|
|
c add Bennington |
| 543 |
|
|
_RL P1atm |
| 544 |
|
|
_RL Rgas |
| 545 |
|
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_RL RT |
| 546 |
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_RL delta |
| 547 |
|
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_RL B1 |
| 548 |
|
|
_RL B |
| 549 |
|
|
INTEGER i |
| 550 |
|
|
INTEGER j |
| 551 |
|
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|
| 552 |
|
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C..................................................................... |
| 553 |
|
|
C OCMIP note: |
| 554 |
|
|
C Calculate all constants needed to convert between various measured |
| 555 |
|
|
C carbon species. References for each equation are noted in the code. |
| 556 |
|
|
C Once calculated, the constants are |
| 557 |
|
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C stored and passed in the common block "const". The original version |
| 558 |
|
|
C of this code was based on the code by dickson in Version 2 of |
| 559 |
|
|
C Handbook of Methods C for the Analysis of the Various Parameters of |
| 560 |
|
|
C the Carbon Dioxide System in Seawater , DOE, 1994 (SOP No. 3, p25-26). |
| 561 |
|
|
C.................................................................... |
| 562 |
|
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|
| 563 |
|
|
do i=imin,imax |
| 564 |
|
|
do j=jmin,jmax |
| 565 |
|
|
if (hFacC(i,j,1,bi,bj).gt.0. _d 0) then |
| 566 |
|
|
t = ttemp(i,j) |
| 567 |
|
|
s = stemp(i,j) |
| 568 |
|
|
C terms used more than once |
| 569 |
|
|
tk = 273.15 _d 0 + t |
| 570 |
|
|
tk100 = tk/100. _d 0 |
| 571 |
|
|
tk1002=tk100*tk100 |
| 572 |
|
|
invtk=1.0 _d 0/tk |
| 573 |
|
|
dlogtk=log(tk) |
| 574 |
|
|
is=19.924 _d 0*s/(1000. _d 0-1.005 _d 0*s) |
| 575 |
|
|
is2=is*is |
| 576 |
|
|
sqrtis=sqrt(is) |
| 577 |
|
|
s2=s*s |
| 578 |
|
|
sqrts=sqrt(s) |
| 579 |
|
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s15=s**1.5 _d 0 |
| 580 |
|
|
scl=s/1.80655 _d 0 |
| 581 |
|
|
C ----------------------------------------------------------------------- |
| 582 |
|
|
C added by Val Bennington Nov 2010 |
| 583 |
|
|
C Fugacity Factor needed for non-ideality in ocean |
| 584 |
|
|
C ff used for atmospheric correction for water vapor and pressure |
| 585 |
|
|
C Weiss (1974) Marine Chemistry |
| 586 |
|
|
P1atm = 1.01325 _d 0 ! bars |
| 587 |
|
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Rgas = 83.1451 _d 0 ! bar*cm3/(mol*K) |
| 588 |
|
|
RT = Rgas*tk |
| 589 |
|
|
delta = (57.7 _d 0 - 0.118 _d 0*tk) |
| 590 |
|
|
B1 = -1636.75 _d 0 + 12.0408 _d 0*tk - 0.0327957 _d 0*tk*tk |
| 591 |
|
|
B = B1 + 3.16528 _d 0*tk*tk*tk*(0.00001 _d 0) |
| 592 |
|
|
fugf(i,j,bi,bj) = exp( (B+2. _d 0*delta) * P1atm / RT) |
| 593 |
|
|
C------------------------------------------------------------------------ |
| 594 |
|
|
C f = k0(1-pH2O)*correction term for non-ideality |
| 595 |
|
|
C Weiss & Price (1980, Mar. Chem., 8, 347-359; Eq 13 with table 6 values) |
| 596 |
|
|
ff(i,j,bi,bj) = exp(-162.8301 _d 0 + 218.2968 _d 0/tk100 + |
| 597 |
|
|
& 90.9241 _d 0*log(tk100) - 1.47696 _d 0*tk1002 + |
| 598 |
|
|
& s * (.025695 _d 0 - .025225 _d 0*tk100 + |
| 599 |
|
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& 0.0049867 _d 0*tk1002)) |
| 600 |
|
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C------------------------------------------------------------------------ |
| 601 |
|
|
C K0 from Weiss 1974 |
| 602 |
|
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ak0(i,j,bi,bj) = exp(93.4517 _d 0/tk100 - 60.2409 _d 0 + |
| 603 |
|
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& 23.3585 _d 0 * log(tk100) + |
| 604 |
|
|
& s * (0.023517 _d 0 - 0.023656 _d 0*tk100 + |
| 605 |
|
|
& 0.0047036 _d 0*tk1002)) |
| 606 |
|
|
C------------------------------------------------------------------------ |
| 607 |
|
|
C k1 = [H][HCO3]/[H2CO3] |
| 608 |
|
|
C k2 = [H][CO3]/[HCO3] |
| 609 |
|
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C Millero p.664 (1995) using Mehrbach et al. data on seawater scale |
| 610 |
|
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ak1(i,j,bi,bj)=10.**(-1. _d 0*(3670.7 _d 0*invtk - |
| 611 |
|
|
& 62.008 _d 0 + 9.7944 _d 0*dlogtk - |
| 612 |
|
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& 0.0118 _d 0 * s + 0.000116 _d 0*s2)) |
| 613 |
|
|
ak2(i,j,bi,bj)=10.**(-1. _d 0*(1394.7 _d 0*invtk+ 4.777 _d 0- |
| 614 |
|
|
& 0.0184 _d 0*s + 0.000118 _d 0*s2)) |
| 615 |
|
|
C------------------------------------------------------------------------ |
| 616 |
|
|
C kb = [H][BO2]/[HBO2] |
| 617 |
|
|
C Millero p.669 (1995) using data from dickson (1990) |
| 618 |
|
|
akb(i,j,bi,bj)=exp((-8966.90 _d 0- 2890.53 _d 0*sqrts - |
| 619 |
|
|
& 77.942 _d 0*s + 1.728 _d 0*s15 - 0.0996 _d 0*s2)*invtk + |
| 620 |
|
|
& (148.0248 _d 0 + 137.1942 _d 0*sqrts + 1.62142 _d 0*s) + |
| 621 |
|
|
& (-24.4344 _d 0 - 25.085 _d 0*sqrts - 0.2474 _d 0*s) * |
| 622 |
|
|
& dlogtk + 0.053105 _d 0*sqrts*tk) |
| 623 |
|
|
C------------------------------------------------------------------------ |
| 624 |
|
|
C k1p = [H][H2PO4]/[H3PO4] |
| 625 |
|
|
C DOE(1994) eq 7.2.20 with footnote using data from Millero (1974) |
| 626 |
|
|
ak1p(i,j,bi,bj) = exp(-4576.752 _d 0*invtk + 115.525 _d 0 - |
| 627 |
|
|
& 18.453 _d 0*dlogtk + |
| 628 |
|
|
& (-106.736 _d 0*invtk + 0.69171 _d 0)*sqrts + |
| 629 |
|
|
& (-0.65643 _d 0*invtk - 0.01844 _d 0)*s) |
| 630 |
|
|
C------------------------------------------------------------------------ |
| 631 |
|
|
C k2p = [H][HPO4]/[H2PO4] |
| 632 |
|
|
C DOE(1994) eq 7.2.23 with footnote using data from Millero (1974)) |
| 633 |
|
|
ak2p(i,j,bi,bj) = exp(-8814.715 _d 0*invtk + 172.0883 _d 0 - |
| 634 |
|
|
& 27.927 _d 0*dlogtk + |
| 635 |
|
|
& (-160.340 _d 0*invtk + 1.3566 _d 0) * sqrts + |
| 636 |
|
|
& (0.37335 _d 0*invtk - 0.05778 _d 0) * s) |
| 637 |
|
|
C------------------------------------------------------------------------ |
| 638 |
|
|
C k3p = [H][PO4]/[HPO4] |
| 639 |
|
|
C DOE(1994) eq 7.2.26 with footnote using data from Millero (1974) |
| 640 |
|
|
ak3p(i,j,bi,bj) = exp(-3070.75 _d 0*invtk - 18.141 _d 0 + |
| 641 |
|
|
& (17.27039 _d 0*invtk + 2.81197 _d 0) * |
| 642 |
|
|
& sqrts + (-44.99486 _d 0*invtk - 0.09984 _d 0) * s) |
| 643 |
|
|
C------------------------------------------------------------------------ |
| 644 |
|
|
C ksi = [H][SiO(OH)3]/[Si(OH)4] |
| 645 |
|
|
C Millero p.671 (1995) using data from Yao and Millero (1995) |
| 646 |
|
|
aksi(i,j,bi,bj) = exp(-8904.2 _d 0*invtk + 117.385 _d 0 - |
| 647 |
|
|
& 19.334 _d 0*dlogtk + |
| 648 |
|
|
& (-458.79 _d 0*invtk + 3.5913 _d 0) * sqrtis + |
| 649 |
|
|
& (188.74 _d 0*invtk - 1.5998 _d 0) * is + |
| 650 |
|
|
& (-12.1652 _d 0*invtk + 0.07871 _d 0) * is2 + |
| 651 |
|
|
& log(1.0 _d 0-0.001005 _d 0*s)) |
| 652 |
|
|
C------------------------------------------------------------------------ |
| 653 |
|
|
C kw = [H][OH] |
| 654 |
|
|
C Millero p.670 (1995) using composite data |
| 655 |
|
|
akw(i,j,bi,bj) = exp(-13847.26 _d 0*invtk + 148.9652 _d 0 - |
| 656 |
|
|
& 23.6521 _d 0*dlogtk + |
| 657 |
|
|
& (118.67 _d 0*invtk - 5.977 _d 0 + 1.0495 _d 0 * dlogtk) |
| 658 |
|
|
& * sqrts - 0.01615 _d 0 * s) |
| 659 |
|
|
C------------------------------------------------------------------------ |
| 660 |
|
|
C ks = [H][SO4]/[HSO4] |
| 661 |
|
|
C dickson (1990, J. chem. Thermodynamics 22, 113) |
| 662 |
|
|
aks(i,j,bi,bj)=exp(-4276.1 _d 0*invtk + 141.328 _d 0 - |
| 663 |
|
|
& 23.093 _d 0*dlogtk + |
| 664 |
|
|
& (-13856. _d 0*invtk + 324.57 _d 0 - 47.986 _d 0*dlogtk)*sqrtis+ |
| 665 |
|
|
& (35474. _d 0*invtk - 771.54 _d 0 + 114.723 _d 0*dlogtk)*is - |
| 666 |
|
|
& 2698. _d 0*invtk*is**1.5 _d 0 + 1776. _d 0*invtk*is2 + |
| 667 |
|
|
& log(1.0 _d 0 - 0.001005 _d 0*s)) |
| 668 |
|
|
C------------------------------------------------------------------------ |
| 669 |
|
|
C kf = [H][F]/[HF] |
| 670 |
|
|
C dickson and Riley (1979) -- change pH scale to total |
| 671 |
|
|
akf(i,j,bi,bj)=exp(1590.2 _d 0*invtk - 12.641 _d 0 + |
| 672 |
|
|
& 1.525 _d 0*sqrtis + log(1.0 _d 0 - 0.001005 _d 0*s) + |
| 673 |
|
|
& log(1.0 _d 0 + (0.1400 _d 0/96.062 _d 0)*(scl)/aks(i,j,bi,bj))) |
| 674 |
|
|
C------------------------------------------------------------------------ |
| 675 |
|
|
C Calculate concentrations for borate, sulfate, and fluoride |
| 676 |
|
|
C Uppstrom (1974) |
| 677 |
|
|
bt(i,j,bi,bj) = 0.000232 _d 0 * scl/10.811 _d 0 |
| 678 |
|
|
C Morris & Riley (1966) |
| 679 |
|
|
st(i,j,bi,bj) = 0.14 _d 0 * scl/96.062 _d 0 |
| 680 |
|
|
C Riley (1965) |
| 681 |
|
|
ft(i,j,bi,bj) = 0.000067 _d 0 * scl/18.9984 _d 0 |
| 682 |
|
|
C------------------------------------------------------------------------ |
| 683 |
|
|
else |
| 684 |
|
|
c add Bennington |
| 685 |
|
|
fugf(i,j,bi,bj)=0. _d 0 |
| 686 |
|
|
ff(i,j,bi,bj)=0. _d 0 |
| 687 |
|
|
ak0(i,j,bi,bj)= 0. _d 0 |
| 688 |
|
|
ak1(i,j,bi,bj)= 0. _d 0 |
| 689 |
|
|
ak2(i,j,bi,bj)= 0. _d 0 |
| 690 |
|
|
akb(i,j,bi,bj)= 0. _d 0 |
| 691 |
|
|
ak1p(i,j,bi,bj) = 0. _d 0 |
| 692 |
|
|
ak2p(i,j,bi,bj) = 0. _d 0 |
| 693 |
|
|
ak3p(i,j,bi,bj) = 0. _d 0 |
| 694 |
|
|
aksi(i,j,bi,bj) = 0. _d 0 |
| 695 |
|
|
akw(i,j,bi,bj) = 0. _d 0 |
| 696 |
|
|
aks(i,j,bi,bj)= 0. _d 0 |
| 697 |
|
|
akf(i,j,bi,bj)= 0. _d 0 |
| 698 |
|
|
bt(i,j,bi,bj) = 0. _d 0 |
| 699 |
|
|
st(i,j,bi,bj) = 0. _d 0 |
| 700 |
|
|
ft(i,j,bi,bj) = 0. _d 0 |
| 701 |
|
|
endif |
| 702 |
|
|
end do |
| 703 |
|
|
end do |
| 704 |
|
|
|
| 705 |
|
|
RETURN |
| 706 |
|
|
END |
| 707 |
|
|
|
| 708 |
|
|
C---+----1----+----2----+----3----+----4----+----5----+----6----+----7-|--+----| |
| 709 |
|
|
|
| 710 |
|
|
CBOP |
| 711 |
|
|
subroutine CARBON_COEFFS_PRESSURE_DEP( |
| 712 |
|
|
I ttemp,stemp, |
| 713 |
|
|
I bi,bj,iMin,iMax,jMin,jMax, |
| 714 |
|
|
I Klevel,myThid) |
| 715 |
|
|
|
| 716 |
|
|
C !DESCRIPTION: |
| 717 |
|
|
C *==========================================================* |
| 718 |
|
|
C | SUBROUTINE CARBON_COEFFS | |
| 719 |
|
|
C | determine coefficients for surface carbon chemistry | |
| 720 |
|
|
C | adapted from OCMIP2: SUBROUTINE CO2CALC | |
| 721 |
|
|
C | mick follows, oct 1999 | |
| 722 |
|
|
C | minor changes to tidy, swd aug 2002 | |
| 723 |
|
|
C | MODIFIED FOR PRESSURE DEPENDENCE | |
| 724 |
|
|
C | Karsten Friis and Mick Follows 2004 | |
| 725 |
|
|
C *==========================================================* |
| 726 |
|
|
C INPUT |
| 727 |
|
|
C diclocal = total inorganic carbon (mol/m^3) |
| 728 |
|
|
C where 1 T = 1 metric ton = 1000 kg |
| 729 |
|
|
C ta = total alkalinity (eq/m^3) |
| 730 |
|
|
C pt = inorganic phosphate (mol/^3) |
| 731 |
|
|
C sit = inorganic silicate (mol/^3) |
| 732 |
|
|
C t = temperature (degrees C) |
| 733 |
|
|
C s = salinity (PSU) |
| 734 |
|
|
C OUTPUT |
| 735 |
|
|
C IMPORTANT: Some words about units - (JCO, 4/4/1999) |
| 736 |
|
|
C - Models carry tracers in mol/m^3 (on a per volume basis) |
| 737 |
|
|
C - Conversely, this routine, which was written by observationalists |
| 738 |
|
|
C (C. Sabine and R. Key), passes input arguments in umol/kg |
| 739 |
|
|
C (i.e., on a per mass basis) |
| 740 |
|
|
C - I have changed things slightly so that input arguments are in mol/m^3, |
| 741 |
|
|
C - Thus, all input concentrations (diclocal, ta, pt, and st) should be |
| 742 |
|
|
C given in mol/m^3; output arguments "co2star" and "dco2star" |
| 743 |
|
|
C are likewise be in mol/m^3. |
| 744 |
|
|
C |
| 745 |
|
|
C NOW INCLUDES: |
| 746 |
|
|
C PRESSURE DEPENDENCE of K1, K2, solubility product of calcite |
| 747 |
|
|
C based on Takahashi, GEOSECS Atlantic Report, Vol. 1 (1981) |
| 748 |
|
|
C |
| 749 |
|
|
C-------------------------------------------------------------------------- |
| 750 |
|
|
|
| 751 |
|
|
implicit none |
| 752 |
|
|
|
| 753 |
|
|
C === Global variables === |
| 754 |
|
|
#include "SIZE.h" |
| 755 |
|
|
#include "DYNVARS.h" |
| 756 |
|
|
#include "EEPARAMS.h" |
| 757 |
|
|
#include "PARAMS.h" |
| 758 |
|
|
#include "GRID.h" |
| 759 |
|
|
#include "FFIELDS.h" |
| 760 |
|
|
#include "BLING_VARS.h" |
| 761 |
|
|
C == Routine arguments == |
| 762 |
|
|
C ttemp and stemp are local theta and salt arrays |
| 763 |
|
|
C dont really need to pass T and S in, could use theta, salt in |
| 764 |
|
|
C common block in DYNVARS.h, but this way keeps subroutine more |
| 765 |
|
|
C general |
| 766 |
|
|
_RL ttemp(1-OLx:sNx+OLx,1-OLy:sNy+OLy) |
| 767 |
|
|
_RL stemp(1-OLx:sNx+OLx,1-OLy:sNy+OLy) |
| 768 |
|
|
INTEGER bi,bj,iMin,iMax,jMin,jMax |
| 769 |
|
|
C K is depth index |
| 770 |
|
|
INTEGER Klevel |
| 771 |
|
|
INTEGER myThid |
| 772 |
|
|
CEOP |
| 773 |
|
|
|
| 774 |
|
|
C LOCAL VARIABLES |
| 775 |
|
|
_RL t |
| 776 |
|
|
_RL s |
| 777 |
|
|
_RL tk |
| 778 |
|
|
_RL tk100 |
| 779 |
|
|
_RL tk1002 |
| 780 |
|
|
_RL dlogtk |
| 781 |
|
|
_RL sqrtis |
| 782 |
|
|
_RL sqrts |
| 783 |
|
|
_RL s15 |
| 784 |
|
|
_RL scl |
| 785 |
|
|
_RL s2 |
| 786 |
|
|
_RL invtk |
| 787 |
|
|
_RL is |
| 788 |
|
|
_RL is2 |
| 789 |
|
|
INTEGER i |
| 790 |
|
|
INTEGER j |
| 791 |
|
|
INTEGER k |
| 792 |
|
|
_RL bdepth |
| 793 |
|
|
_RL cdepth |
| 794 |
|
|
_RL pressc |
| 795 |
|
|
_RL Ksp_T_Calc |
| 796 |
|
|
_RL Ksp_T_Arag |
| 797 |
|
|
_RL xvalue |
| 798 |
|
|
_RL zdum |
| 799 |
|
|
_RL tmpa1 |
| 800 |
|
|
_RL tmpa2 |
| 801 |
|
|
_RL tmpa3 |
| 802 |
|
|
_RL logKspc |
| 803 |
|
|
_RL logKspa |
| 804 |
|
|
_RL dv |
| 805 |
|
|
_RL dk |
| 806 |
|
|
_RL pfactor |
| 807 |
|
|
_RL bigR |
| 808 |
|
|
|
| 809 |
|
|
C..................................................................... |
| 810 |
|
|
C OCMIP note: |
| 811 |
|
|
C Calculate all constants needed to convert between various measured |
| 812 |
|
|
C carbon species. References for each equation are noted in the code. |
| 813 |
|
|
C Once calculated, the constants are |
| 814 |
|
|
C stored and passed in the common block "const". The original version |
| 815 |
|
|
C of this code was based on the code by dickson in Version 2 of |
| 816 |
|
|
C Handbook of Methods C for the Analysis of the Various Parameters of |
| 817 |
|
|
C the Carbon Dioxide System in Seawater , DOE, 1994 (SOP No. 3, p25-26). |
| 818 |
|
|
C.................................................................... |
| 819 |
|
|
|
| 820 |
|
|
c determine pressure (bar) from depth |
| 821 |
|
|
c 1 BAR at z=0m (atmos pressure) |
| 822 |
|
|
c use UPPER surface of cell so top layer pressure = 0 bar |
| 823 |
|
|
c for surface exchange coeffs |
| 824 |
|
|
|
| 825 |
|
|
cmick.............................. |
| 826 |
|
|
c write(6,*)'Klevel ',klevel |
| 827 |
|
|
|
| 828 |
|
|
bdepth = 0.0d0 |
| 829 |
|
|
cdepth = 0.0d0 |
| 830 |
|
|
pressc = 1.0d0 |
| 831 |
|
|
do k = 1,Klevel |
| 832 |
|
|
cdepth = bdepth + 0.5d0*drF(k) |
| 833 |
|
|
bdepth = bdepth + drF(k) |
| 834 |
|
|
pressc = 1.0d0 + 0.1d0*cdepth |
| 835 |
|
|
end do |
| 836 |
|
|
|
| 837 |
|
|
do i=imin,imax |
| 838 |
|
|
do j=jmin,jmax |
| 839 |
|
|
if (hFacC(i,j,Klevel,bi,bj).gt.0.d0) then |
| 840 |
|
|
t = ttemp(i,j) |
| 841 |
|
|
s = stemp(i,j) |
| 842 |
|
|
C terms used more than once |
| 843 |
|
|
tk = 273.15 + t |
| 844 |
|
|
tk100 = tk/100.0 |
| 845 |
|
|
tk1002=tk100*tk100 |
| 846 |
|
|
invtk=1.0/tk |
| 847 |
|
|
dlogtk=log(tk) |
| 848 |
|
|
is=19.924*s/(1000.-1.005*s) |
| 849 |
|
|
is2=is*is |
| 850 |
|
|
sqrtis=sqrt(is) |
| 851 |
|
|
s2=s*s |
| 852 |
|
|
sqrts=sqrt(s) |
| 853 |
|
|
s15=s**1.5 |
| 854 |
|
|
scl=s/1.80655 |
| 855 |
|
|
|
| 856 |
|
|
C------------------------------------------------------------------------ |
| 857 |
|
|
C f = k0(1-pH2O)*correction term for non-ideality |
| 858 |
|
|
C Weiss & Price (1980, Mar. Chem., 8, 347-359; Eq 13 with table 6 values) |
| 859 |
|
|
ff(i,j,bi,bj) = exp(-162.8301 + 218.2968/tk100 + |
| 860 |
|
|
& 90.9241*log(tk100) - 1.47696*tk1002 + |
| 861 |
|
|
& s * (.025695 - .025225*tk100 + |
| 862 |
|
|
& 0.0049867*tk1002)) |
| 863 |
|
|
C------------------------------------------------------------------------ |
| 864 |
|
|
C K0 from Weiss 1974 |
| 865 |
|
|
ak0(i,j,bi,bj) = exp(93.4517/tk100 - 60.2409 + |
| 866 |
|
|
& 23.3585 * log(tk100) + |
| 867 |
|
|
& s * (0.023517 - 0.023656*tk100 + |
| 868 |
|
|
& 0.0047036*tk1002)) |
| 869 |
|
|
C------------------------------------------------------------------------ |
| 870 |
|
|
C k1 = [H][HCO3]/[H2CO3] |
| 871 |
|
|
C k2 = [H][CO3]/[HCO3] |
| 872 |
|
|
C Millero p.664 (1995) using Mehrbach et al. data on seawater scale |
| 873 |
|
|
ak1(i,j,bi,bj)=10**(-1*(3670.7*invtk - |
| 874 |
|
|
& 62.008 + 9.7944*dlogtk - |
| 875 |
|
|
& 0.0118 * s + 0.000116*s2)) |
| 876 |
|
|
ak2(i,j,bi,bj)=10**(-1*(1394.7*invtk + 4.777 - |
| 877 |
|
|
& 0.0184*s + 0.000118*s2)) |
| 878 |
|
|
C NOW PRESSURE DEPENDENCE: |
| 879 |
|
|
c Following Takahashi (1981) GEOSECS report - quoting Culberson and |
| 880 |
|
|
c Pytkowicz (1968) |
| 881 |
|
|
c pressc = pressure in bars |
| 882 |
|
|
ak1(i,j,bi,bj) = ak1(i,j,bi,bj)* |
| 883 |
|
|
& exp( (24.2-0.085*t)*(pressc-1.0)/(83.143*tk) ) |
| 884 |
|
|
c FIRST GO FOR K2: According to GEOSECS (1982) report |
| 885 |
|
|
c ak2(i,j,bi,bj) = ak2(i,j,bi,bj)* |
| 886 |
|
|
c & exp( (26.4-0.040*t)*(pressc-1.0)/(83.143*tk) ) |
| 887 |
|
|
c SECOND GO FOR K2: corrected coeff according to CO2sys documentation |
| 888 |
|
|
c E. Lewis and D. Wallace (1998) ORNL/CDIAC-105 |
| 889 |
|
|
ak2(i,j,bi,bj) = ak2(i,j,bi,bj)* |
| 890 |
|
|
& exp( (16.4-0.040*t)*(pressc-1.0)/(83.143*tk) ) |
| 891 |
|
|
C------------------------------------------------------------------------ |
| 892 |
|
|
C kb = [H][BO2]/[HBO2] |
| 893 |
|
|
C Millero p.669 (1995) using data from dickson (1990) |
| 894 |
|
|
akb(i,j,bi,bj)=exp((-8966.90 - 2890.53*sqrts - 77.942*s + |
| 895 |
|
|
& 1.728*s15 - 0.0996*s2)*invtk + |
| 896 |
|
|
& (148.0248 + 137.1942*sqrts + 1.62142*s) + |
| 897 |
|
|
& (-24.4344 - 25.085*sqrts - 0.2474*s) * |
| 898 |
|
|
& dlogtk + 0.053105*sqrts*tk) |
| 899 |
|
|
C Mick and Karsten - Dec 04 |
| 900 |
|
|
C ADDING pressure dependence based on Millero (1995), p675 |
| 901 |
|
|
C with additional info from CO2sys documentation (E. Lewis and |
| 902 |
|
|
C D. Wallace, 1998 - see endnotes for commentary on Millero, 95) |
| 903 |
|
|
bigR = 83.145 |
| 904 |
|
|
dv = -29.48 + 0.1622*t + 2.608d-3*t*t |
| 905 |
|
|
dk = -2.84d-3 |
| 906 |
|
|
pfactor = - (dv/(bigR*tk))*pressc |
| 907 |
|
|
& + (0.5*dk/(bigR*tk))*pressc*pressc |
| 908 |
|
|
akb(i,j,bi,bj) = akb(i,j,bi,bj)*exp(pfactor) |
| 909 |
|
|
C------------------------------------------------------------------------ |
| 910 |
|
|
C k1p = [H][H2PO4]/[H3PO4] |
| 911 |
|
|
C DOE(1994) eq 7.2.20 with footnote using data from Millero (1974) |
| 912 |
|
|
ak1p(i,j,bi,bj) = exp(-4576.752*invtk + 115.525 - |
| 913 |
|
|
& 18.453*dlogtk + |
| 914 |
|
|
& (-106.736*invtk + 0.69171)*sqrts + |
| 915 |
|
|
& (-0.65643*invtk - 0.01844)*s) |
| 916 |
|
|
C------------------------------------------------------------------------ |
| 917 |
|
|
C k2p = [H][HPO4]/[H2PO4] |
| 918 |
|
|
C DOE(1994) eq 7.2.23 with footnote using data from Millero (1974)) |
| 919 |
|
|
ak2p(i,j,bi,bj) = exp(-8814.715*invtk + 172.0883 - |
| 920 |
|
|
& 27.927*dlogtk + |
| 921 |
|
|
& (-160.340*invtk + 1.3566) * sqrts + |
| 922 |
|
|
& (0.37335*invtk - 0.05778) * s) |
| 923 |
|
|
C------------------------------------------------------------------------ |
| 924 |
|
|
C k3p = [H][PO4]/[HPO4] |
| 925 |
|
|
C DOE(1994) eq 7.2.26 with footnote using data from Millero (1974) |
| 926 |
|
|
ak3p(i,j,bi,bj) = exp(-3070.75*invtk - 18.141 + |
| 927 |
|
|
& (17.27039*invtk + 2.81197) * |
| 928 |
|
|
& sqrts + (-44.99486*invtk - 0.09984) * s) |
| 929 |
|
|
C------------------------------------------------------------------------ |
| 930 |
|
|
C ksi = [H][SiO(OH)3]/[Si(OH)4] |
| 931 |
|
|
C Millero p.671 (1995) using data from Yao and Millero (1995) |
| 932 |
|
|
aksi(i,j,bi,bj) = exp(-8904.2*invtk + 117.385 - |
| 933 |
|
|
& 19.334*dlogtk + |
| 934 |
|
|
& (-458.79*invtk + 3.5913) * sqrtis + |
| 935 |
|
|
& (188.74*invtk - 1.5998) * is + |
| 936 |
|
|
& (-12.1652*invtk + 0.07871) * is2 + |
| 937 |
|
|
& log(1.0-0.001005*s)) |
| 938 |
|
|
C------------------------------------------------------------------------ |
| 939 |
|
|
C kw = [H][OH] |
| 940 |
|
|
C Millero p.670 (1995) using composite data |
| 941 |
|
|
akw(i,j,bi,bj) = exp(-13847.26*invtk + 148.9652 - |
| 942 |
|
|
& 23.6521*dlogtk + |
| 943 |
|
|
& (118.67*invtk - 5.977 + 1.0495 * dlogtk) * |
| 944 |
|
|
& sqrts - 0.01615 * s) |
| 945 |
|
|
C------------------------------------------------------------------------ |
| 946 |
|
|
C ks = [H][SO4]/[HSO4] |
| 947 |
|
|
C dickson (1990, J. chem. Thermodynamics 22, 113) |
| 948 |
|
|
aks(i,j,bi,bj)=exp(-4276.1*invtk + 141.328 - |
| 949 |
|
|
& 23.093*dlogtk + |
| 950 |
|
|
& (-13856*invtk + 324.57 - 47.986*dlogtk)*sqrtis + |
| 951 |
|
|
& (35474*invtk - 771.54 + 114.723*dlogtk)*is - |
| 952 |
|
|
& 2698*invtk*is**1.5 + 1776*invtk*is2 + |
| 953 |
|
|
& log(1.0 - 0.001005*s)) |
| 954 |
|
|
C------------------------------------------------------------------------ |
| 955 |
|
|
C kf = [H][F]/[HF] |
| 956 |
|
|
C dickson and Riley (1979) -- change pH scale to total |
| 957 |
|
|
akf(i,j,bi,bj)=exp(1590.2*invtk - 12.641 + 1.525*sqrtis + |
| 958 |
|
|
& log(1.0 - 0.001005*s) + |
| 959 |
|
|
& log(1.0 + (0.1400/96.062)*(scl)/aks(i,j,bi,bj))) |
| 960 |
|
|
C------------------------------------------------------------------------ |
| 961 |
|
|
C Calculate concentrations for borate, sulfate, and fluoride |
| 962 |
|
|
C Uppstrom (1974) |
| 963 |
|
|
bt(i,j,bi,bj) = 0.000232 * scl/10.811 |
| 964 |
|
|
C Morris & Riley (1966) |
| 965 |
|
|
st(i,j,bi,bj) = 0.14 * scl/96.062 |
| 966 |
|
|
C Riley (1965) |
| 967 |
|
|
ft(i,j,bi,bj) = 0.000067 * scl/18.9984 |
| 968 |
|
|
C------------------------------------------------------------------------ |
| 969 |
|
|
C solubility product for calcite |
| 970 |
|
|
caxx and aragonite |
| 971 |
|
|
C |
| 972 |
|
|
c Following Takahashi (1982) GEOSECS handbook |
| 973 |
|
|
C NOT SURE THIS IS WORKING??? |
| 974 |
|
|
C Ingle et al. (1973) |
| 975 |
|
|
c Ksp_T_Calc = ( -34.452 - 39.866*(s**0.333333) |
| 976 |
|
|
c & + 110.21*log(s) - 7.5752d-6 * (tk**2.0) |
| 977 |
|
|
c & ) * 1.0d-7 |
| 978 |
|
|
c with pressure dependence Culberson and Pytkowicz (1968) |
| 979 |
|
|
c xvalue = (36-0.20*t)*(pressc-1.0)/(83.143*tk) |
| 980 |
|
|
c Ksp_TP_Calc(i,j,bi,bj) = Ksp_T_Calc*exp(xvalue) |
| 981 |
|
|
c |
| 982 |
|
|
c |
| 983 |
|
|
C Following Mucci (1983) - from Zeebe/Wolf-Gladrow equic.m |
| 984 |
|
|
tmpa1 = - 171.9065 - (0.077993*tk) + (2839.319/tk) |
| 985 |
|
|
& + (71.595*log10(tk)) |
| 986 |
|
|
tmpa2 = +(-0.77712 + (0.0028426*tk) + (178.34/tk) )*sqrts |
| 987 |
|
|
tmpa3 = -(0.07711*s) + (0.0041249*s15) |
| 988 |
|
|
logKspc = tmpa1 + tmpa2 + tmpa3 |
| 989 |
|
|
Ksp_T_Calc = 10.0**logKspc |
| 990 |
|
|
C |
| 991 |
|
|
tmpa1 = - 171.945 - (0.077993*tk) + (2903.293/tk) |
| 992 |
|
|
& + (71.595*log10(tk)) |
| 993 |
|
|
tmpa2 = +(-0.068393 + (0.0017276*tk) + (88.135/tk) )*sqrts |
| 994 |
|
|
tmpa3 = -(0.10018*s) + (0.0059415*s15) |
| 995 |
|
|
logKspa = tmpa1 + tmpa2 + tmpa3 |
| 996 |
|
|
Ksp_T_Arag = 10.0**logKspa |
| 997 |
|
|
|
| 998 |
|
|
c with pressure dependence Culberson and Pytkowicz (1968) |
| 999 |
|
|
c xvalue = (36.0-0.20*t)*(pressc-1.0)/(83.143*tk) |
| 1000 |
|
|
c Ksp_TP_Calc(i,j,bi,bj) = Ksp_T_Calc*exp(xvalue) |
| 1001 |
|
|
|
| 1002 |
|
|
c alternative pressure depdendence |
| 1003 |
|
|
c following Millero (1995) but using info from Appendix A11 of |
| 1004 |
|
|
c Zeebe and Wolf-Gladrow (2001) book |
| 1005 |
|
|
c dv = -48.6 - 0.5304*t |
| 1006 |
|
|
c dk = -11.76d-3 - 0.3692*t |
| 1007 |
|
|
c xvalue = - (dv/(bigR*tk))*pressc |
| 1008 |
|
|
c & + (0.5*dk/(bigR*tk))*pressc*pressc |
| 1009 |
|
|
c Ksp_TP_Calc(i,j,bi,bj) = Ksp_T_Calc*exp(xvalue) |
| 1010 |
|
|
|
| 1011 |
|
|
c alternative pressure dependence from Ingle (1975) |
| 1012 |
|
|
|
| 1013 |
|
|
zdum = (pressc*10.0d0 - 10.0d0)/10.0d0 |
| 1014 |
|
|
xvalue = ( (48.8d0 - 0.53d0*t)*zdum |
| 1015 |
|
|
& + (-0.00588d0 + 0.0001845d0*t)*zdum*zdum) |
| 1016 |
|
|
& / (188.93d0*(t + 273.15d0)) |
| 1017 |
|
|
|
| 1018 |
|
|
Ksp_TP_Calc(i,j,bi,bj) = Ksp_T_Calc*10**(xvalue) |
| 1019 |
|
|
Ksp_TP_Arag(i,j,bi,bj) = Ksp_T_Arag*10**(xvalue) |
| 1020 |
|
|
|
| 1021 |
|
|
|
| 1022 |
|
|
C------------------------------------------------------------------------ |
| 1023 |
|
|
else |
| 1024 |
|
|
ff(i,j,bi,bj)=0.d0 |
| 1025 |
|
|
ak0(i,j,bi,bj)= 0.d0 |
| 1026 |
|
|
ak1(i,j,bi,bj)= 0.d0 |
| 1027 |
|
|
ak2(i,j,bi,bj)= 0.d0 |
| 1028 |
|
|
akb(i,j,bi,bj)= 0.d0 |
| 1029 |
|
|
ak1p(i,j,bi,bj) = 0.d0 |
| 1030 |
|
|
ak2p(i,j,bi,bj) = 0.d0 |
| 1031 |
|
|
ak3p(i,j,bi,bj) = 0.d0 |
| 1032 |
|
|
aksi(i,j,bi,bj) = 0.d0 |
| 1033 |
|
|
akw(i,j,bi,bj) = 0.d0 |
| 1034 |
|
|
aks(i,j,bi,bj)= 0.d0 |
| 1035 |
|
|
akf(i,j,bi,bj)= 0.d0 |
| 1036 |
|
|
bt(i,j,bi,bj) = 0.d0 |
| 1037 |
|
|
st(i,j,bi,bj) = 0.d0 |
| 1038 |
|
|
ft(i,j,bi,bj) = 0.d0 |
| 1039 |
|
|
Ksp_TP_Calc(i,j,bi,bj) = 0.d0 |
| 1040 |
|
|
Ksp_TP_Arag(i,j,bi,bj) = 0.d0 |
| 1041 |
|
|
endif |
| 1042 |
|
|
end do |
| 1043 |
|
|
end do |
| 1044 |
|
|
|
| 1045 |
|
|
return |
| 1046 |
|
|
end |
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